%mem=20000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3ph2-sch2ch3-ts_6311+Gd

-1 1
 C                  0.32089400    0.02470400    0.00236900
 H                  0.34109800   -0.34698200   -1.00605700
 H                  0.47889000    1.07197700    0.18636800
 H                 -0.01756800   -0.61166900    0.79905800
 H                 -2.44265400    0.75100100    0.99176200
 H                 -2.54675800   -0.79291900   -0.39365900
 P                 -2.17330400    0.58672300   -0.40229300
 S                  2.27384022   -0.46981472    0.38177944
 C                  3.14206734    0.45274159   -0.86860911
 H                  3.71066794   -0.21901607   -1.47716067
 H                  2.43690755    0.97705965   -1.47913367
 C                  4.08977289    1.46311075   -0.19584737
 H                  4.79493348    0.93879232    0.41467595
 H                  4.61168344    2.01768229   -0.94748544
 H                  3.52117218    2.13486709    0.41270554

