%mem=20000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3ph2-cf3-ts_6311+Gd

-1 1
 C                  0.32625711    0.03554542   -0.02361360
 H                  0.34646111   -0.33614058   -1.03203960
 H                  0.48425311    1.08281842    0.16038540
 H                 -0.01220489   -0.60082758    0.77307540
 H                 -2.45598383    0.72783598    1.04791514
 H                 -2.56008783   -0.81608402   -0.33750586
 P                 -2.18663383    0.56355798   -0.34613986
 C                  2.23594236   -0.34306365    0.19741386
 F                  2.67453348   -1.07171357   -0.85101693
 F                  2.42790226   -1.03696465    1.33940895
 F                  2.92116471    0.81862558    0.25613750

