%mem=120000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3ph2-oTs-ts_6311+Gd

-1 1
 C                  0.05849300    0.16951900    0.04261300
 H                  0.35541900    0.27434500   -0.98473500
 H                  0.25532000    0.97774400    0.72267000
 H                 -0.19699900   -0.80054600    0.42756100
 H                 -2.65508600    0.33456500    0.93332800
 H                 -2.53867700   -0.44310400   -0.99025100
 P                 -2.22477100    0.79337700   -0.34859700
 C                  6.24259114   -3.07980748    1.00764986
 C                  6.02492214   -1.81260748    0.45934386
 C                  4.71451514   -1.36268648    0.23924986
 C                  3.58156314   -2.13657448    0.54795886
 C                  3.84283714   -3.40369948    1.09742286
 C                  5.14218614   -3.87948648    1.32858586
 H                  6.87424814   -1.18064748    0.20560386
 H                  4.59004114   -0.36603248   -0.19156014
 H                  3.01036914   -4.06131248    1.36105686
 H                  5.29914414   -4.86835548    1.75588886
 C                  7.67532806   -3.58775929    1.25432755
 H                  8.02988142   -4.09338363    0.38052211
 H                  8.31552922   -2.75819715    1.47082033
 H                  7.67604616   -4.26462454    2.08303312
 S                  1.92554364   -1.55001528    0.26169372
 O                  1.90136339   -0.19550023    0.36146770
 O                  1.08202311   -2.09144534    1.19430371
 O                  1.55609805   -1.88919371   -0.87924083

