%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3cf3-OTf-ts_6311+Gd_ch2cl2_aq

-1 1
 C	-0.930290000	-0.376966000	 0.263099000
 H	-0.696856000	-0.901237000	-0.649337000
 H	-0.259408000	-0.525917000	 1.093658000
 H	-1.366198000	 0.603628000	 0.157215000
 F	 0.965210000	 1.718237000	-1.717953000
 F	 2.258579000	 0.185824000	-0.827399000
 F	 1.634804000	 1.921112000	 0.361310000
 C	 1.097281000	 0.950694000	-0.527024000
 S	-3.032343000	-1.075551000	 2.011025000
 O	-2.242932000	-0.349148000	 2.999620000
 O	-2.255389000	-1.329352000	 0.696239000
 O	-3.764328000	-2.273313000	 2.399611000
 C	-4.352612000	 0.143860000	 1.432625000
 F	-5.100767000	-0.398358000	 0.467949000
 F	-5.142411000	 0.469443000	 2.461583000
 F	-3.778271000	 1.255903000	 0.959231000




