%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sh-OTf-ts_6311+Gd_ch2cl2_aq

-1 1
 S	 1.128548000	 1.009890000	-0.798929000
 O	 1.543295000	 2.197690000	-0.055822000
 O	 1.543878000	 0.854320000	-2.189247000
 O	 1.342065000	-0.294039000	-0.014539000
 C	 1.421228000	-0.304707000	 1.761074000
 H	 2.198102000	 0.423999000	 1.916845000
 H	 0.408898000	-0.023144000	 1.997709000
 H	 1.677708000	-1.348276000	 1.820937000
 S	 1.573234000	-0.505082000	 4.503163000
 H	 2.876777000	-0.874970000	 4.455078000
 C	-0.755193000	 1.110118000	-0.862978000
 F	-1.257516000	 1.181589000	 0.376667000
 F	-1.129502000	 2.201890000	-1.541138000
 F	-1.264939000	 0.032775000	-1.469537000




