%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3och3-OTf-ts_6311+Gd_ch2cl2_aq

-1 1
 S	 1.130803000	 0.937937000	-0.751726000
 O	 1.547124000	 2.148250000	-0.054527000
 O	 1.577448000	 0.682431000	-2.113064000
 O	 1.323860000	-0.344794000	 0.105944000
 C	 1.361102000	-0.281048000	 1.738565000
 H	 2.155513000	 0.416429000	 1.950815000
 H	 0.369124000	 0.037232000	 2.016958000
 H	 1.583527000	-1.318625000	 1.925674000
 O	 1.448106000	-0.410271000	 4.115444000
 C	 2.766698000	-0.605262000	 4.410359000
 H	 2.953233000	-0.970881000	 5.449723000
 H	 3.278094000	-1.361778000	 3.756329000
 H	 3.404252000	 0.312979000	 4.318780000
 C	-0.752658000	 1.038582000	-0.857359000
 F	-1.248683000	-0.071946000	-1.408251000
 F	-1.276588000	 1.188412000	 0.363338000
 F	-1.099265000	 2.088194000	-1.609775000




