%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3OTf-br_6311+Gd_ch2cl2_aq

-1 1
 S	 1.200218000	 0.858810000	-0.845989000
 O	 1.809905000	 2.031423000	-0.217870000
 O	 1.448632000	 0.608514000	-2.263749000
 O	 1.355810000	-0.417367000	-0.021944000
 C	 1.431480000	-0.386693000	 1.830922000
 H	 1.783727000	 0.622487000	 1.961163000
 H	 0.389375000	-0.604900000	 1.982402000
 H	 2.142542000	-1.192898000	 1.864388000
 Br	 1.561914000	-0.505376000	 4.523336000
 C	-0.655793000	 1.172884000	-0.726727000
 F	-0.985167000	 2.263198000	-1.430969000
 F	-1.010719000	 1.366005000	 0.551447000
 F	-1.344929000	 0.130301000	-1.206513000




