%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3oTf-oTf-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 1.333566000	 0.568747000	 0.690003000
 H	 0.619916000	 0.347245000	-0.082472000
 H	 1.803633000	 1.535863000	 0.720446000
 H	 1.584330000	-0.167002000	 1.437104000
 S	 3.436411000	-1.393009000	-0.397566000
 O	 3.478579000	-1.881232000	 0.984704000
 O	 2.799231000	-0.027953000	-0.536274000
 O	 4.642102000	-1.531320000	-1.216209000
 S	-0.838233000	 0.491121000	 2.855814000
 O	-1.686562000	 1.290594000	 3.741151000
 O	-0.140105000	 1.332988000	 1.810176000
 O	 0.028124000	-0.526578000	 3.459607000
 C	 2.164245000	-2.504884000	-1.236269000
 F	 2.575808000	-3.780500000	-1.225002000
 F	 1.971657000	-2.133838000	-2.510456000
 F	 0.987420000	-2.432973000	-0.594554000
 C	-2.051255000	-0.504329000	 1.809296000
 F	-2.911057000	 0.305112000	 1.174450000
 F	-1.390169000	-1.222952000	 0.887449000
 F	-2.753348000	-1.346909000	 2.579533000




