%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3OTf-OTs-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 1.405411000	 0.462524000	 0.832637000
 H	 0.747356000	 0.012694000	 0.112411000
 H	 1.648831000	 1.507381000	 0.748653000
 H	 1.934244000	-0.146864000	 1.544957000
 S	 3.479931000	-1.254546000	-0.690941000
 O	 4.131391000	-1.703601000	 0.560310000
 O	 2.922271000	 0.161218000	-0.559692000
 O	 4.295789000	-1.373530000	-1.918941000
 S	-0.764801000	-0.226506000	 2.763266000
 O	-1.519693000	 0.277706000	 3.909591000
 O	-0.018769000	 0.887067000	 2.043031000
 O	 0.030724000	-1.444104000	 2.929038000
 C	-2.085565000	-0.692549000	 1.496093000
 F	-2.938897000	 0.322710000	 1.305983000
 F	-1.522795000	-0.997811000	 0.318061000
 F	-2.779595000	-1.757059000	 1.922593000
 C	 2.017124000	-2.288979000	-0.910271000
 C	 1.525749000	-3.034260000	 0.158099000
 C	 1.340015000	-2.267255000	-2.130146000
 C	 0.347869000	-3.762092000	 0.000685000
 H	 2.055050000	-3.041640000	 1.102610000
 C	 0.163083000	-2.996458000	-2.271228000
 H	 1.728401000	-1.688439000	-2.960935000
 C	-0.355142000	-3.749934000	-1.208308000
 H	-0.035747000	-4.335929000	 0.838903000
 H	-0.362405000	-2.979004000	-3.221645000
 C	-1.659338000	-4.490914000	-1.350847000
 H	-1.694598000	-5.371912000	-0.705212000
 H	-2.500017000	-3.847017000	-1.067396000
 H	-1.830220000	-4.813279000	-2.381103000




