%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3OTf-ph2-ts_6311+Gd_ch2cl2_aq

-1 1
 C	-0.282137000	-0.856834000	 0.020276000
 H	-0.130288000	-1.000793000	 1.077809000
 H	-0.653637000	 0.107113000	-0.289574000
 H	 0.411475000	-1.350539000	-0.641252000
 H	 1.994564000	 1.370225000	-0.922512000
 H	 1.277689000	 1.928186000	 0.947226000
 S	-2.447169000	-1.983957000	-1.445024000
 O	-1.672844000	-1.862999000	-0.113114000
 O	-1.651948000	-1.576336000	-2.599339000
 O	-3.199337000	-3.232048000	-1.489580000
 C	-3.747486000	-0.630858000	-1.238813000
 F	-4.522871000	-0.882299000	-0.179826000
 F	-3.153921000	 0.556479000	-1.065437000
 F	-4.516255000	-0.572192000	-2.332102000
 P	 2.115681000	 0.890567000	 0.422230000




