%mem=3000MB
%nprocshared=4
#p opt=(maxstep=4,ts,noeigentest,calcfc) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-OTf-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.102923000	-0.483597000	 0.695263000
 H	 0.823619000	 0.158163000	 0.213229000
 H	-0.169896000	-0.229709000	 1.707381000
 H	-0.667302000	-0.911462000	 0.073675000
 H	-2.891221000	 1.208831000	 0.571830000
 H	-1.805777000	 1.459002000	-1.332599000
 S	 1.769434000	-2.689268000	-0.003310000
 O	 1.049335000	-1.876432000	 1.094930000
 O	 2.068933000	-4.036407000	 0.467735000
 O	 1.178572000	-2.500475000	-1.324930000
 As	-1.638289000	 1.977573000	 0.108417000
 C	 3.439489000	-1.811414000	-0.081053000
 F	 4.214402000	-2.396273000	-1.001588000
 F	 4.057437000	-1.870351000	 1.102513000
 F	 3.270490000	-0.525587000	-0.414015000




