%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3och2ch3-OTf-ts_6311+Gd_ch2cl2_aq

-1 1
 S	 1.124365000	 1.041715000	-0.743064000
 O	 1.326372000	 2.189710000	 0.132247000
 O	 1.620572000	 1.065431000	-2.111308000
 O	 1.510644000	-0.303290000	-0.068349000
 C	 1.585764000	-0.449911000	 1.566838000
 H	 2.409399000	 0.189778000	 1.838462000
 H	 0.611069000	-0.134838000	 1.904230000
 H	 1.777887000	-1.508666000	 1.611642000
 O	 1.751985000	-0.884071000	 3.894308000
 C	 0.542537000	-1.406480000	 4.250293000
 H	-0.289146000	-0.652344000	 4.212599000
 H	 0.196666000	-2.217913000	 3.553385000
 C	 0.515609000	-2.011182000	 5.666923000
 H	 0.772570000	-1.247907000	 6.411050000
 H	-0.472103000	-2.421483000	 5.922458000
 H	 1.253849000	-2.817899000	 5.750494000
 C	-0.748372000	 0.847902000	-0.897804000
 F	-1.046118000	-0.217721000	-1.645733000
 F	-1.299103000	 0.695160000	 0.311349000
 F	-1.264174000	 1.939165000	-1.473357000




