%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sch3-OTf-ts_6311+Gd_ch2cl2_aq

-1 1
 S	 1.242059000	 1.091970000	-0.831194000
 O	 1.782927000	 2.076423000	 0.101909000
 O	 1.441941000	 1.269585000	-2.264368000
 O	 1.562593000	-0.361088000	-0.425220000
 C	 1.615056000	-0.837937000	 1.236926000
 H	 1.960739000	 0.061239000	 1.719804000
 H	 0.587473000	-1.126518000	 1.376628000
 H	 2.333240000	-1.632163000	 1.115398000
 C	 0.212731000	-0.303316000	 4.116310000
 H	 0.515283000	 0.668577000	 3.710985000
 H	-0.705222000	-0.605438000	 3.600515000
 S	 1.550500000	-1.564775000	 3.925321000
 H	-0.038406000	-0.153790000	 5.171098000
 C	-0.627629000	 1.163334000	-0.575649000
 F	-0.923875000	 0.984692000	 0.717690000
 F	-1.090461000	 2.357380000	-0.962430000
 F	-1.236955000	 0.212390000	-1.290924000




