%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3c6h5-OTf-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 3.309329000	 0.556008000	-0.399475000
 H	 3.050076000	 1.486685000	-0.879618000
 H	 3.106197000	 0.509303000	 0.657997000
 H	 3.083599000	-0.333544000	-0.965898000
 C	 0.650187000	 0.085895000	-0.067750000
 C	 0.753666000	-1.168958000	 0.573257000
 C	-0.670674000	 0.590291000	-0.118814000
 C	-0.335865000	-1.865388000	 1.116132000
 H	 1.735784000	-1.643389000	 0.666839000
 C	-1.783153000	-0.077993000	 0.416249000
 H	-0.861510000	 1.555952000	-0.594541000
 C	-1.619167000	-1.317421000	 1.040036000
 H	-0.187850000	-2.831122000	 1.598400000
 H	-2.776125000	 0.365309000	 0.348133000
 H	-2.472822000	-1.844685000	 1.458409000
 S	 5.871941000	-0.554822000	-0.352491000
 O	 7.233521000	-0.189043000	-0.715249000
 O	 4.952591000	 0.692775000	-0.468394000
 O	 5.261367000	-1.756764000	-0.907626000
 C	 5.905804000	-0.834918000	 1.515437000
 F	 6.713931000	-1.862038000	 1.797406000
 F	 6.355216000	 0.254862000	 2.143102000
 F	 4.676639000	-1.115799000	 1.960408000




