%mem=40000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nch33-och3-ts_6311+Gd

0 1
 C                  0.05265800   -0.16521700    0.30143700
 H                  0.31094800   -0.51967900   -0.68277500
 H                  0.21161700    0.86687100    0.56074200
 H                 -0.30199200   -0.85448100    1.04956500
 N                 -1.79040900    0.22755700   -0.28510400
 C                 -2.38033600   -1.02973500   -0.76386100
 H                 -1.78739800   -1.41710700   -1.59382200
 H                 -2.37882600   -1.76295900    0.04413500
 H                 -3.41105200   -0.87706800   -1.10396200
 C                 -1.70075700    1.22389400   -1.36064900
 H                 -1.21372000    2.12411300   -0.98282100
 H                 -1.10721800    0.82008500   -2.18233900
 H                 -2.69552800    1.48863300   -1.73685700
 C                 -2.51661600    0.75449900    0.87838000
 H                 -2.51587500    0.00940600    1.67552700
 H                 -2.02083400    1.65733900    1.23838700
 H                 -3.55352000    0.99712500    0.61908100
 O                  1.87901102   -0.62891411    0.89042121
 C                  2.81826600    0.05775200    0.05904300
 H                  3.75266489   -0.46346043    0.07071828
 H                  2.44489466    0.09815351   -0.94288592
 H                  2.96003763    1.05236204    0.42721644

