%mem=3000MB
%nprocshared=4 
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3sch3-och2ch3-ts_6311+Gd

-1 1
 C                 -0.02500600    0.27798300   -0.04299900
 H                  0.10816500   -0.35157800   -0.90487000
 H                  0.08957800   -0.13657100    0.94158800
 H                 -0.20016500    1.32973700   -0.17315400
 O                  1.98101300    0.69386200   -0.06298100
 C                  2.65227400   -0.53397500    0.05328100
 H                  2.37982900   -1.21910500   -0.77407700
 H                  2.35933300   -1.06262900    0.98227000
 C                  4.17087400   -0.36184800    0.05612100
 H                  4.48716200    0.27420900    0.88975100
 H                  4.67990700   -1.32808300    0.15446500
 H                  4.51028400    0.10704700   -0.87361900
 S                 -2.35576800   -0.18757100   -0.04160800
 C                 -2.68082422    0.84469261    1.37160476
 H                 -2.06926834    0.53007998    2.19131099
 H                 -2.45630323    1.86238289    1.12912421
 H                 -3.71230000    0.76213269    1.64389425

