%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-c6h5-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.054022000	 0.162298000	 0.033557000
 H	 0.362531000	 0.210912000	-0.994961000
 H	 0.286166000	 0.985292000	 0.684937000
 H	-0.233412000	-0.783033000	 0.455819000
 H	-2.767540000	 0.457347000	 0.976355000
 H	-2.669341000	-0.456807000	-1.029177000
 C	 4.965059000	-1.459574000	 0.909711000
 C	 4.717787000	-0.192489000	 0.373903000
 C	 3.397308000	 0.229405000	 0.159732000
 C	 2.281610000	-0.571341000	 0.462152000
 C	 2.572776000	-1.837567000	 0.998923000
 C	 3.882874000	-2.286382000	 1.223731000
 H	 5.984116000	-1.796934000	 1.079666000
 H	 5.552656000	 0.461557000	 0.125320000
 H	 3.249063000	 1.227492000	-0.261456000
 H	 1.756429000	-2.517214000	 1.258206000
 H	 4.062388000	-3.276259000	 1.641487000
 As	-2.277264000	 0.896915000	-0.413386000




