%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-hcooo-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.621363000	 0.172228000	-0.037716000
 H	 0.553662000	 0.192597000	-1.113116000
 H	 0.621978000	 1.098886000	 0.509411000
 H	 0.518333000	-0.760818000	 0.485278000
 H	-2.108272000	-0.081297000	 1.497947000
 H	-2.221445000	-1.156789000	-0.424651000
 H	 3.463746000	-0.595060000	 2.917836000
 C	 3.028754000	-0.858712000	 1.939226000
 O	 3.060019000	 0.236873000	 1.185904000
 O	 2.614562000	-1.957835000	 1.654129000
 O	 2.533037000	 0.074707000	-0.152138000
 As	-2.065523000	 0.311725000	 0.010058000




