%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-nch33-ts_6311+Gd_ch2cl2_aq

0 1
 C	 0.240713000	 0.025364000	-0.224086000
 H	 0.099299000	-0.879604000	-0.790628000
 H	 0.291655000	 0.966760000	-0.744795000
 H	 0.051112000	 0.018467000	 0.835633000
 H	-2.500098000	 1.346036000	 0.713244000
 H	-2.715670000	-0.843704000	 0.558708000
 N	 2.189092000	-0.183979000	-0.048645000
 C	 2.679342000	 0.960029000	 0.733165000
 H	 3.765487000	 0.904392000	 0.869929000
 H	 2.433903000	 1.887724000	 0.214569000
 H	 2.198277000	 0.964618000	 1.712106000
 C	 2.425581000	-1.457351000	 0.646020000
 H	 1.998014000	-2.274319000	 0.063382000
 H	 3.498681000	-1.637427000	 0.779213000
 H	 1.945473000	-1.432634000	 1.625109000
 C	 2.750750000	-0.194493000	-1.406679000
 H	 2.318104000	-1.020632000	-1.972609000
 H	 2.508031000	 0.742885000	-1.908790000
 H	 3.840166000	-0.312795000	-1.379042000
 As	-2.480510000	 0.313579000	-0.429063000




