%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-och3-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.240759000	 0.016916000	-0.042163000
 H	 0.256217000	-0.152261000	-1.104975000
 H	 0.519414000	 0.979735000	 0.350119000
 H	-0.042438000	-0.775497000	 0.625634000
 H	-2.439596000	 0.693574000	 1.311463000
 H	-2.735097000	-0.639827000	-0.421479000
 O	 2.144526000	-0.625828000	 0.111795000
 C	 2.924121000	 0.204254000	-0.666171000
 H	 2.887799000	 1.273995000	-0.355707000
 H	 3.993986000	-0.081121000	-0.632126000
 H	 2.645259000	 0.199307000	-1.745167000
 As	-2.202198000	 0.787777000	-0.206175000




