%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-ooh-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.524542000	-0.025884000	 0.047905000
 H	 0.641610000	-0.472965000	-0.923507000
 H	 0.704642000	 1.028772000	 0.175372000
 H	 0.230802000	-0.631683000	 0.885131000
 H	-2.325584000	 0.712360000	 0.979663000
 H	-2.345276000	-1.029706000	-0.374264000
 O	 2.441554000	-0.353678000	 0.474495000
 O	 2.601729000	-1.808450000	 0.548399000
 H	 2.793629000	-2.050501000	-0.370160000
 As	-1.955305000	 0.454309000	-0.491476000




