%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-oTs-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.114725000	 0.004351000	 0.403035000
 H	 0.309940000	 0.405299000	-0.577662000
 H	 0.238143000	 0.658885000	 1.249270000
 H	-0.587654000	-0.808104000	 0.492080000
 H	-3.011172000	 0.763608000	 1.276705000
 H	-2.909648000	 0.461832000	-0.906088000
 C	 6.295102000	-3.002459000	 1.104364000
 C	 6.073549000	-2.016521000	 0.133259000
 C	 4.788602000	-1.718319000	-0.310949000
 C	 3.706776000	-2.417987000	 0.221368000
 C	 3.896072000	-3.400336000	 1.191259000
 C	 5.188312000	-3.685765000	 1.624579000
 H	 6.917720000	-1.474662000	-0.282636000
 H	 4.628639000	-0.956832000	-1.065413000
 H	 3.046840000	-3.937642000	 1.597076000
 H	 5.337499000	-4.452654000	 2.378699000
 C	 7.693126000	-3.341394000	 1.552108000
 H	 8.134543000	-4.100808000	 0.896624000
 H	 8.347977000	-2.467007000	 1.521299000
 H	 7.704100000	-3.742696000	 2.568325000
 S	 2.041842000	-2.007155000	-0.309380000
 O	 1.661378000	-0.875926000	 0.691966000
 O	 1.191798000	-3.196185000	-0.110151000
 O	 2.112298000	-1.481324000	-1.686177000
 As	-2.382574000	 1.514371000	 0.087155000




