%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-sch2ch3-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.437392000	 0.013879000	 0.167123000
 H	 0.578125000	 0.227801000	-0.877522000
 H	 0.690988000	 0.749723000	 0.906742000
 H	-0.064490000	-0.888517000	 0.464607000
 H	-2.430404000	 0.556878000	 1.305936000
 H	-2.523446000	-0.036896000	-0.816249000
 S	 2.624495000	-1.049201000	 0.272413000
 C	 3.421240000	 0.123205000	-0.910799000
 H	 4.394300000	-0.294024000	-1.190104000
 H	 2.823538000	 0.157414000	-1.829013000
 C	 3.605818000	 1.537637000	-0.365503000
 H	 4.225280000	 1.533171000	 0.536728000
 H	 4.092409000	 2.184335000	-1.107598000
 H	 2.645587000	 1.993065000	-0.106808000
 As	-1.979188000	 1.169789000	-0.031478000




