%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-sch3-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.282810000	-0.044339000	 0.018335000
 H	 0.292028000	-0.290432000	-1.028262000
 H	 0.552795000	 0.945531000	 0.339395000
 H	-0.107433000	-0.749110000	 0.729656000
 H	-2.472745000	 0.855126000	 1.204900000
 H	-2.762896000	-0.588521000	-0.436454000
 S	 2.563607000	-0.820286000	 0.289642000
 C	 3.195806000	 0.410007000	-0.923958000
 H	 2.975806000	 1.433749000	-0.604736000
 H	 4.280470000	 0.318277000	-1.028867000
 H	 2.749942000	 0.260371000	-1.912472000
 As	-2.225573000	 0.848184000	-0.313925000




