%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3ash2-sh-ts_6311+Gd_ch2cl2_aq

-1 1
 C	 0.326312000	 0.027565000	 0.004886000
 H	 0.337016000	-0.340565000	-1.005073000
 H	 0.471753000	 1.075782000	 0.192882000
 H	-0.045204000	-0.603263000	 0.792236000
 H	-2.565707000	 0.810315000	 1.055087000
 H	-2.697225000	-0.821124000	-0.422446000
 H	 3.044250000	 0.232621000	-0.578702000
 S	 2.604118000	-0.550386000	 0.434133000
 As	-2.307699000	 0.667509000	-0.455686000




