%mem=16000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3och3-och3-ts_6311+Gd_new

-1 1
 C                  0.00000200   -0.59718600    0.00009800
 H                  0.03702400   -0.05756700    0.93218900
 H                 -0.03703200   -0.05772100   -0.93208100
 H                  0.00001400   -1.67378100    0.00018600
 O                  1.94233900   -0.61746400   -0.08386700
 C                  2.33814184   -1.96373431   -0.03405486
 H                  3.43488558   -2.05895782   -0.06084418
 H                  1.94587956   -2.55370868   -0.88402209
 H                  1.99522681   -2.47333847    0.88630381
 O                 -1.94233500   -0.61749400    0.08407000
 C                 -2.36845700    0.71641500   -0.01930300
 H                 -3.46570500    0.79078100    0.03681700
 H                 -1.96286400    1.35547600    0.78781700
 H                 -2.06529000    1.18658900   -0.97398100

