%mem=3000MB
%nprocshared=4
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3f-oh-ts_6311+Gd_new

-1 1
 C                 -0.09693200    0.01115700    0.01139300
 H                  0.00481000    1.08080300    0.00465800
 H                 -0.01306800   -0.53400100   -0.91122700
 H                 -0.02487600   -0.51245000    0.94738000
 N                  2.10977700    0.00685800    0.06591200
 H                  2.31076600   -0.98826200   -0.07177100
 H                  2.31502000    0.42205300   -0.84797700
 S                 -1.95894700    0.10785000   -0.01469600
 H                 -2.39623399    1.34271035   -0.01469600

