%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sch3-cl-ts_6311+Gd_new

-1 1
 C	 0.195593000	-0.059076000	 0.019999000
 H	 0.011129000	 0.385532000	 0.981786000
 H	 0.145928000	-1.130805000	-0.063114000
 H	 0.015423000	 0.527876000	-0.863127000
 S	-2.506960000	-0.144856000	 0.005679000
 Cl	 2.358094000	 0.125700000	 0.037730000
 C	-2.550581000	 1.700017000	-0.025579000
 H	-1.969106000	 2.128764000	 0.797706000
 H	-2.144532000	 2.097681000	-0.961904000
 H	-3.576989000	 2.067511000	 0.070489000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


