%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sch3-och3-ts_6311+Gd_new

-1 1
 C	-0.052881000	 0.252878000	-0.139087000
 H	 0.117659000	-0.388315000	-0.986989000
 H	 0.051296000	-0.140815000	 0.857023000
 H	-0.207371000	 1.305856000	-0.290164000
 O	 1.933944000	 0.687931000	-0.112834000
 C	 2.611590000	-0.492408000	 0.097689000
 H	 3.710112000	-0.345924000	 0.124078000
 H	 2.430891000	-1.260910000	-0.690275000
 H	 2.353818000	-0.993071000	 1.060724000
 S	-2.348461000	-0.165266000	-0.119277000
 C	-2.623464000	 0.833585000	 1.398673000
 H	-2.077538000	 0.418113000	 2.252176000
 H	-2.293489000	 1.868058000	 1.256959000
 H	-3.685768000	 0.852651000	 1.656972000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


