%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sch3-cf3-ts_6311+Gd_new

-1 1
 C	 0.327152000	-0.236343000	-0.180446000
 H	 0.648934000	-1.253798000	-0.041612000
 H	 0.435397000	 0.467734000	 0.626144000
 H	 0.095837000	 0.114923000	-1.170899000
 S	-1.888513000	-0.668874000	 0.325594000
 C	-2.389492000	 1.087853000	 0.122280000
 H	-1.860386000	 1.735935000	 0.828487000
 H	-2.179527000	 1.445706000	-0.890910000
 H	-3.461964000	 1.199712000	 0.302510000
 C	 2.459121000	 0.246599000	-0.678618000
 F	 3.399945000	 0.073500000	 0.352996000
 F	 3.035480000	-0.483171000	-1.734218000
 F	 2.690977000	 1.577115000	-1.073527000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


