%mem=16000MB
%nprocshared=12
#p opt=(ts,calcfc,noeigentest,maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sch3-sh-ts_6311+Gd_new

-1 1
 C	 0.087576000	 0.005671000	-0.015940000
 H	 0.193080000	 0.038757000	 1.052226000
 H	 0.004948000	 0.916539000	-0.579315000
 H	 0.173822000	-0.931548000	-0.534717000
 S	 2.587476000	 0.179943000	-0.136007000
 H	-2.453001000	 0.932322000	 0.791482000
 S	-2.304611000	-0.243220000	 0.136025000
 C	 2.794926000	-1.362395000	 0.849166000
 H	 3.855880000	-1.593691000	 0.981532000
 H	 2.348836000	-1.264917000	 1.844404000
 H	 2.326732000	-2.219104000	 0.353333000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-311+g*


