%mem=3000MB
%nprocshared=4 
#p opt=maxstep=2 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm empiricaldispersion=gd3

ch3sch2ch3-c6h5_6311+Gd

-1 1
 C                  1.95791906    1.68018622   -3.92567276
 H                  1.38476606    2.47134222   -3.43929876
 H                  1.65848606    1.59901322   -4.97213376
 H                  1.75346106    0.73346922   -3.42371776
 C                 -1.37876100    0.96538200    1.08526800
 C                 -2.65186400    1.54634200    1.31346500
 C                 -3.85229700    1.04810100    0.78396300
 C                 -3.83782300   -0.09031500   -0.02566800
 C                 -2.61310400   -0.70950900   -0.28732300
 C                 -1.43142100   -0.18430700    0.25789100
 H                 -2.73106100    2.43923400    1.93857700
 H                 -4.79666800    1.54522800    1.00015000
 H                 -4.75991200   -0.48643000   -0.44228600
 H                 -2.58089200   -1.59838300   -0.91553400
 H                 -0.50782100   -0.71432700    0.01466300
 S                  3.75026706    2.00556022   -3.79294376
 C                  3.81011806    3.59579522   -4.68907176
 H                  3.46412006    3.47310622   -5.71734276
 H                  3.19877206    4.34697022   -4.18541376
 C                  5.27446627    4.07218292   -4.70748578
 H                  5.88036286    3.34352003   -5.20431544
 H                  5.33959043    5.00486893   -5.22782765
 H                  5.62088184    4.19915633   -3.70310836

