%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm empiricaldispersion=gd3

ch3sch2ch3-Ts_6311+Gd

-1 1
 C                  0.06174800   -0.07211800   -0.01057800
 H                  0.45451400    0.41248100    0.88455800
 H                  0.39958400   -1.10864900   -0.02910300
 H                  0.43737600    0.43878300   -0.89844300
 S                 -1.76490400   -0.08291200    0.00641300
 C                 -2.06133400    1.73294300    0.03352300
 H                 -1.58401200    2.16814500   -0.84829000
 H                 -1.57090700    2.14417700    0.91962600
 C                 -3.55276200    2.04171500    0.04873300
 H                 -4.04232100    1.62242000    0.93223300
 H                 -3.70762300    3.12439300    0.06460900
 H                 -4.05521000    1.64648600   -0.83861200
 C                  7.22282441   -3.07843510    0.78866760
 C                  5.97881809   -2.62423134    1.22898581
 C                  5.48390365   -1.41583397    0.74842279
 C                  6.22439367   -0.65707579   -0.16108765
 C                  7.46228403   -1.12226413   -0.58942480
 C                  7.98318963   -2.33835891   -0.12178791
 H                  7.60275360   -4.02496249    1.16007548
 H                  5.40025528   -3.21172292    1.93138708
 H                  5.83705323    0.28249085   -0.53865687
 H                  8.03421906   -0.53458422   -1.30111997
 C                  9.33154499   -2.81834143   -0.59027989
 H                  9.40339573   -2.79174447   -1.68131178
 H                 10.12937691   -2.17671444   -0.20207676
 H                  9.53251521   -3.83907243   -0.25909188
 S                  3.90241668   -0.77964440    1.33653030
 O                  3.18740529   -0.26340013    0.12900391
 O                  4.22494262    0.31361900    2.30747707
 O                  3.19599479   -1.92598189    1.98188122

