%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm empiricaldispersion=gd3

ch3sch3-oTs_6311+Gd

-1 1
 C                 -0.09620299   -1.09019828    5.01137180
 H                  0.50341950   -0.28632674    5.43270953
 H                 -1.05201934   -1.13715878    5.53375720
 H                  0.41995335   -2.04107997    5.12645239
 S                 -0.47903317   -0.76083120    3.24514455
 C                  5.13422400    1.58843900   -2.58756900
 C                  5.29935900    1.21051700   -1.26010200
 C                  5.33806700   -0.14635200   -0.93328300
 C                  5.21416300   -1.11599500   -1.92264300
 C                  5.05400000   -0.72159800   -3.25130300
 C                  5.00832900    0.63065400   -3.60448000
 H                  5.09784000    2.64379200   -2.84004400
 H                  5.39083200    1.96545500   -0.48755200
 H                  5.23801500   -2.16774700   -1.66499300
 H                  4.95381200   -1.48029200   -4.02099200
 C                  4.81759200    1.06023000   -5.03509700
 H                  5.70700900    1.57548700   -5.41170000
 H                  4.62080900    0.20765100   -5.68794600
 H                  3.98116900    1.75956800   -5.12571700
 S                  5.43475300   -0.62785600    0.80008400
 O                  5.86955300   -2.05694100    0.82185000
 O                  4.05721700   -0.44266000    1.35820000
 O                  6.42753500    0.29164900    1.43580300
 C                  1.20414238   -0.73125757    2.66683196
 H                  1.21600675   -0.54609704    1.61304127
 H                  1.74104371    0.04467988    3.17136942
 H                  1.66717282   -1.67457818    2.86844800

