%mem=16000MB
%nprocshared=12
#p opt=maxstep=4 freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3sch3-cl_6311+Gd_aq

-1 1
 C                 -0.88439400   -0.21314600    0.00358300
 H                 -0.56287865   -0.84838146    0.83054355
 H                 -0.59523794   -0.68383773   -0.93711647
 H                 -0.39323969    0.75838318    0.07868152
 S                 -2.70086300   -0.02308300    0.00018700
 Cl                 3.13131300   -0.00341900    0.00486700
 C                 -2.78956800    1.80086000    0.01201400
 H                 -2.31015000    2.21739100   -0.87602300
 H                 -3.84315500    2.08418500    0.01155200
 H                 -2.31410900    2.20559800    0.90759800

