%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sch3-och3_6311+Gd_aq

-1 1
 C	-1.102889000	-0.218015000	 0.035073000
 H	-0.707073000	 0.166295000	 0.976903000
 H	-0.884293000	-1.285107000	-0.027779000
 H	-0.613922000	 0.289478000	-0.798264000
 S	-2.916317000	-0.012145000	-0.044374000
 O	 2.715712000	 0.053861000	 0.150428000
 C	 4.056950000	 0.000569000	-0.064494000
 H	 4.452069000	 0.771187000	-0.783874000
 H	 4.690312000	 0.147528000	 0.854549000
 H	 4.430138000	-0.972994000	-0.488998000
 C	-2.999965000	 1.808604000	 0.076643000
 H	-4.052175000	 2.097753000	 0.044053000
 H	-2.566392000	 2.155985000	 1.017054000
 H	-2.477749000	 2.278291000	-0.759831000




