%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sch3-cf3_6311+Gd_aq

-1 1
 C	-1.226465000	-0.532124000	-0.091516000
 H	-0.846906000	-0.102658000	 0.837036000
 H	-0.840437000	-1.546968000	-0.191811000
 H	-0.878900000	 0.060471000	-0.939122000
 S	-3.051938000	-0.624646000	-0.067473000
 C	-3.423526000	 1.157311000	 0.086128000
 H	-3.032676000	 1.711462000	-0.770232000
 H	-4.508825000	 1.271474000	 0.115059000
 H	-3.000415000	 1.565270000	 1.006810000
 C	 2.411814000	-0.363020000	-0.103092000
 F	 1.955810000	 0.989892000	 0.039213000
 F	 3.179057000	-0.491687000	 1.104554000
 F	 3.473650000	-0.165517000	-1.049250000




