%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sh-f_6311+Gd_aq

-1 1
 C	-0.043492000	-0.190067000	 0.003744000
 H	 0.391385000	 0.250458000	 0.899466000
 H	 0.167103000	-1.259558000	-0.000654000
 H	 0.398124000	 0.259134000	-0.884331000
 H	-1.909925000	 1.342685000	 0.006192000
 S	-1.875100000	-0.009208000	-0.001855000
 F	 3.470766000	 0.072477000	-0.001307000




