%mem=16000MB
%nprocshared=12
#p opt=(maxstep=4) freq b3lyp/6-311+G(d) scrf=(smd,solvent=water) empiricaldispersion=gd3 nosymm

ch3sh-cl_6311+Gd_aq

-1 1
 C	 0.911300000	 0.186532000	 0.005820000
 H	 0.476733000	-0.250960000	 0.903702000
 H	 0.700936000	 1.256193000	-0.001464000
 H	 0.467085000	-0.264958000	-0.880315000
 H	 2.775846000	-1.346610000	 0.009306000
 S	 2.741934000	 0.005268000	-0.002361000
 Cl	-3.149093000	-0.038145000	-0.000135000




