%mem=20000MB
%nprocshared=12
#p opt=(calcf,maxstep=3) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm guess=always empiricaldispersion=gd3
int=superfinegrid

ch3nhcho-nch33_6311+Gd

0 1
 N                 -0.09132500    0.61928300    0.22707900
 H                  0.29965200    1.06683200   -0.58986100
 C                  0.17574500    1.15414700    1.42093900
 O                 -0.23948000    0.70870300    2.50217900
 H                  0.81208300    2.04880800    1.37416800
 C                 -0.91733100   -0.57187000    0.06422100
 H                 -0.97725700   -0.81325100   -0.99460700
 H                 -0.48375300   -1.42091100    0.59418400
 H                 -1.92455700   -0.39889300    0.44873300
 N                 -3.32701000   -3.92114000   -0.05856500
 C                 -4.67333200   -3.69800800   -0.58894700
 H                 -5.08633900   -2.76970300   -0.18846600
 H                 -4.63965400   -3.61376100   -1.67738200
 H                 -5.36581500   -4.51831600   -0.33155200
 C                 -3.37906800   -4.01487000    1.40113100
 H                 -2.37585100   -4.16824900    1.80740000
 H                 -3.77827500   -3.08947400    1.81942600
 H                 -4.01567400   -4.84839100    1.74564700
 C                 -2.77458100   -5.16174900   -0.60626100
 H                 -2.71392300   -5.09816600   -1.69490500
 H                 -1.76725300   -5.32819300   -0.21848900
 H                 -3.38859800   -6.04260300   -0.34982200

