%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3nch33-sh_6311+Gd

0 1
 N                  0.00862800   -0.24731300    0.01665600
 C                  0.26240800   -1.71752500    0.21351400
 H                 -0.26131800   -2.05229600    1.10979400
 H                 -0.10671200   -2.25783700   -0.65476300
 H                  1.33119300   -1.87438900    0.31637400
 C                  0.52372500    0.50346300    1.20884200
 H                  0.33407100    1.56481300    1.06076500
 H                  0.00124900    0.15470400    2.09752100
 H                  1.59142500    0.32283600    1.30689200
 C                  0.71465500    0.22345300   -1.21664300
 H                  0.33739400   -0.32849100   -2.06977800
 H                  0.52310600    1.28751400   -1.34107100
 H                  1.77970100    0.04525300   -1.10186800
 C                 -1.46497500   -0.01103000   -0.11993400
 H                 -1.96762100   -0.36239300    0.78319200
 H                 -1.63449200    1.05536800   -0.26651500
 H                 -1.82967700   -0.56216700   -0.99259700
 S                  1.11280600   -5.10204600    0.15029100
 C                  1.35593600   -6.94723400    0.33240500
 H                  2.21715500   -7.19419300    1.17351900
 H                  0.30476600   -7.47070600    0.68542900
 H                  1.69571000   -7.37324000   -0.72873300

