%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3nch33-cl_6311+Gd

0 1
 N                  0.05456300   -0.26356200    0.02153600
 C                  0.54696800   -1.68286900    0.22836600
 H                  0.14964100   -2.06690900    1.17278300
 H                  0.20574700   -2.29943400   -0.60967700
 H                  1.63356100   -1.67788900    0.25668300
 C                  0.49877200    0.59635300    1.18513900
 H                  0.15676800    1.62069900    1.01963700
 H                  0.06484000    0.19122800    2.10965500
 H                  1.58697700    0.56122900    1.23854100
 C                  0.62902300    0.28196600   -1.26631100
 H                  0.30708400   -0.36598800   -2.09364900
 H                  0.25984900    1.30570200   -1.40862200
 H                  1.71710300    0.27439000   -1.18919300
 C                 -1.43858000   -0.25458100   -0.04500200
 H                 -1.84238000   -0.66367900    0.88298000
 H                 -1.78839400    0.77575100   -0.18831700
 H                 -1.74958200   -0.87779300   -0.89338500
 Cl                 1.84666000   -4.95398500   -0.07712700

