%mem=40000MB
%nprocshared=20
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3 volume

ch3Ts-nch33_6311+Gd

0 1 
 C                  2.77264887    0.77348449   -4.62473337
 C                  2.59944404    1.00161639   -3.26602599
 C                  1.32323787    0.84952076   -2.72010877
 C                  0.23250857    0.47057417   -3.50076032
 C                  0.43101496    0.24802435   -4.86013045
 C                  1.69601511    0.39597661   -5.44162715
 H                  3.75957390    0.89107148   -5.06002643
 H                  3.43857890    1.29377575   -2.64615307
 H                 -0.74967012    0.35097231   -3.06073557
 H                 -0.41202992   -0.04710099   -5.47571582
 C                  1.89966081    0.18225196   -6.91617427
 H                  1.09865068   -0.41936597   -7.34986778
 H                  1.91373953    1.14354245   -7.44120075
 H                  2.85446819   -0.30893247   -7.11843141
 S                  1.10576600    1.07794100   -0.97177900
 O                 -0.31610469    1.28267436   -0.68184517
 O                  2.08036750    2.04066294   -0.46099616
 O                  1.57930100   -0.32782200   -0.31041700
 C                  1.51518800   -0.45269000    1.15046400
 H                  2.11680200    0.32247700    1.61923300
 H                  0.48027100   -0.40399800    1.48361900
 H                  1.93163200   -1.43439800    1.35444500
 N                  1.34532738   -0.73155911    4.43426965
 C                  0.12144674   -0.07725991    4.91894350
 H                  0.13891054    0.95764291    4.64770346
 H                 -0.73276878   -0.54716760    4.47803239
 H                  0.06734695   -0.16599666    5.98388434
 C                  2.51887607   -0.08598556    5.04000743
 H                  3.40972775   -0.56224471    4.68721785
 H                  2.53633946    0.94891722    4.76876718
 H                  2.46477633   -0.17472210    6.10494830
 C                  1.32133544   -2.15334157    4.80690757
 H                  0.46711959   -2.62324854    4.36599633
 H                  2.21218752   -2.62959984    4.45411777
 H                  1.26723570   -2.24207877    5.87184838

