%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm empiricaldispersion=gd3 volume

ch3oTs-sch2ch3_6311+Gd

-1 1
 C                 -2.82028900    0.54715800   -0.93415700
 C                 -1.51319600    0.58954400   -1.40039200
 C                 -0.53728400    1.18647100   -0.59922000
 C                 -0.84847900    1.73238200    0.64869300
 C                 -2.16577800    1.67752800    1.09419900
 C                 -3.17057800    1.09245900    0.30902300
 H                 -3.58755800    0.08844900   -1.54917400
 H                 -1.25974900    0.16424300   -2.36075700
 H                 -0.07888800    2.18387900    1.26207000
 H                 -2.41233000    2.09998600    2.05907500
 C                 -4.59752800    1.06602700    0.78231200
 H                 -4.66746300    1.22509200    1.85988900
 H                 -5.17335200    1.85382900    0.29152000
 H                 -5.07549800    0.11425200    0.53788700
 S                  1.14767700    1.18784200   -1.15497800
 O                  1.90115200    2.21207100   -0.42450900
 O                  1.19594700    1.17976500   -2.61670800
 O                  1.72342200   -0.27402200   -0.75084300
 C                  1.82817300   -0.59220500    0.67923400
 H                  2.44474400    0.14892800    1.18472000
 H                  0.83186000   -0.64943500    1.12284200
 H                  2.30248300   -1.56967500    0.70274800
 C                  0.96027600   -0.50413200    5.94899000
 H                  1.48203900    0.35810300    6.46809500
 H                 -0.13500200   -0.52720300    6.29292800
 S                  1.07169400   -0.29801400    4.10634500
 C                  1.62518223   -1.81895930    6.39701778
 H                  2.65685969   -1.81166175    6.11331308
 H                  1.54826544   -1.91336997    7.46006549
 H                  1.13240162   -2.64539465    5.92896663

