%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm empiricaldispersion=gd3 volume

ch3Ts-cn_6311+Gd

-1 1
 C                  2.77644800    0.80876300   -4.58156700
 C                  2.61711900    1.06542900   -3.22488200
 C                  1.35753100    0.88792800   -2.65847300
 C                  0.26619400    0.45357700   -3.40768700
 C                  0.44649600    0.20338200   -4.76178000
 C                  1.69768500    0.37551200   -5.37089600
 H                  3.74987900    0.94532600   -5.03620900
 H                  3.45634500    1.40068500   -2.62678800
 H                 -0.70776900    0.31826700   -2.94857900
 H                 -0.39699500   -0.13296800   -5.35641300
 C                  1.87540900    0.13733600   -6.84423400
 H                  1.19724200   -0.64140100   -7.20779700
 H                  1.65289600    1.04922900   -7.40661200
 H                  2.89895500   -0.15570400   -7.08260300
 S                  1.14464800    1.18947100   -0.92176000
 O                 -0.25732400    1.49718800   -0.61684800
 O                  2.16274300    2.12460800   -0.43262200
 O                  1.48704100   -0.29841400   -0.35338200
 C                  1.39983500   -0.47955200    1.09627100
 H                  2.10611700    0.17512500    1.60320300
 H                  0.37938700   -0.29928600    1.43388800
 H                  1.66977800   -1.51871400    1.25271400
 C                  1.05772400   -1.27904900    4.29081000
 N                  1.87652200   -0.44095100    4.78677200

