%mem=3000MB
%nprocshared=4 
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm empiricaldispersion=gd3 volume

ch3Ts-c6h5_6311+Gd

-1 1
 C                  2.79200700    0.81653600   -4.72862900
 C                  2.63742000    1.11556700   -3.38002100
 C                  1.38444700    0.93011000   -2.79627900
 C                  0.29627400    0.45030200   -3.52461800
 C                  0.47602800    0.15776400   -4.87170600
 C                  1.71937800    0.33744000   -5.49359800
 H                  3.76155800    0.95834800   -5.19436400
 H                  3.47247900    1.48734300   -2.79890300
 H                 -0.66979800    0.31048400   -3.05502200
 H                 -0.36354500   -0.21504200   -5.44880700
 C                  1.89269000    0.05227800   -6.95982200
 H                  1.19708600   -0.71581700   -7.30392200
 H                  1.69819600    0.95664200   -7.54679900
 H                  2.91116900   -0.26985100   -7.18695000
 S                  1.17678900    1.28487400   -1.07246800
 O                 -0.22752200    1.58739800   -0.77313000
 O                  2.18542600    2.25010600   -0.62024500
 O                  1.53825900   -0.17531100   -0.45542300
 C                  1.45537600   -0.30921900    1.00516800
 H                  2.15561800    0.37357600    1.48439400
 H                  0.43537300   -0.12799900    1.33983900
 H                  1.73958200   -1.33952900    1.19769400
 C                  1.24106300   -0.80326000    4.72246600
 C                  2.31026800   -1.45799700    5.38495300
 C                  0.25701600   -0.30571000    5.61395900
 C                  2.40282300   -1.60777200    6.77722300
 H                  3.12755500   -1.88189900    4.79588600
 C                  0.31714000   -0.43802700    7.00977600
 H                 -0.61460500    0.21817800    5.21341800
 C                  1.39884100   -1.09441700    7.60206300
 H                  3.25429000   -2.12270000    7.21946700
 H                 -0.47580000   -0.03094300    7.63528700
 H                  1.45790500   -1.20374900    8.68156800

