%mem=16000MB
%nprocshared=12
#p opt=maxstep=4 freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3och3-cn_6311+Gd

-1 1
 C                 -0.53446900   -0.29726300    0.00007400
 H                 -0.28372900    0.29161500    0.89033600
 H                  0.05315100   -1.21538100    0.00013100
 H                 -0.28686100    0.28949600   -0.89245700
 O                 -1.91108200   -0.67015300    0.00292300
 C                 -2.77126900    0.46556700    0.00297400
 H                 -2.60673300    1.08432500    0.89410300
 H                 -2.61028300    1.08171100   -0.89061800
 C                 -4.22116624   -0.05345593    0.00660447
 H                 -4.89696280    0.77612167    0.00671833
 H                 -4.38869241   -0.64984158   -0.86583988
 H                 -4.38523922   -0.64726760    0.88145747
C                  2.67122800    0.93138900   -0.00909800
 N                  3.22096200   -0.10615800   -0.00447700

