%mem=4000MB
%nprocshared=4
#p opt freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3och2ch3-nch33_6311+Gd

0 1
 C                 -1.42785000    0.31211800    0.73247400
 H                 -1.23247900   -0.62545900    1.25131500
 H                 -1.26584800    0.20549400   -0.33932800
 H                 -0.82120400    1.11912200    1.14134700
 N                  1.61896500   -1.88564700   -0.51407700
 C                  1.78795300   -0.60070600    0.16762200
 H                  2.85163200   -0.33316100    0.29391400
 H                  1.30709400    0.19548900   -0.40367100
 H                  1.33133300   -0.63659100    1.15843900
 C                  2.22772700   -1.81994600   -1.84421200
 H                  3.30884400   -1.60118500   -1.79926100
 H                  2.09720200   -2.77098000   -2.36504900
 H                  1.74962300   -1.03795500   -2.43811900
 C                  2.25821700   -2.94516200    0.26881500
 H                  3.34024400   -2.77190600    0.40271000
 H                  1.80168900   -3.00874700    1.25893800
 H                  2.12977300   -3.90939200   -0.22771000
 O                 -2.80250768    0.64871241    0.93721891
 C                 -3.09702874    1.87919714    0.27083714
 H                 -2.47762187    2.65652903    0.66705712
 H                 -2.90795131    1.77158615   -0.77681242
 C                 -4.57781802    2.24043661    0.49076702
 H                 -4.76690552    2.34800349    1.53841929
 H                 -4.79818281    3.16117180   -0.00781706
 H                 -5.19722540    1.46312546    0.09450715

