%mem=16000MB
%nprocshared=12
#p opt=maxstep=4 freq b3lyp/6-311+g(d) scrf=(smd,solvent=water) nosymm
empiricaldispersion=gd3

ch3och3-oh_6311+Gd_aq

-1 1
 C                 -0.04524300   -0.37790700    0.00010800
 H                  0.27147300    0.17483900    0.89249200
 H                  0.42392400   -1.36161400   -0.00004300
 H                  0.27167200    0.17520800   -0.89197600
 O                 -1.45720700   -0.58041500   -0.00009300
 C                 -2.17507700    0.64969300    0.00009700
 H                 -1.93968100    1.24313400    0.89257700
 H                 -1.93949200    1.24351900   -0.89207700
 C                 -3.67661235    0.30765274   -0.00013599
 H                 -3.91243296   -0.26355697    0.87336736
 H                 -4.24843012    1.21204448   -0.00000201
 H                 -3.91224810   -0.26318055   -0.87393525
O                  3.35270700   -0.01119900   -0.00016800
 H                  4.31868700    0.01126200    0.00038500

