%mem=3000MB
%nprocshared=4
#p opt=maxstep=4 freq=noraman b3lyp/6-311+g(d) scrf=(smd,solvent=water)
nosymm empiricaldispersion=gd3

ch3och3-oTs_6311+Gd

-1 1
 C                  1.81703800   -1.27127900   -0.07871700
 H                  0.93637300   -0.76578600    0.33785200
 H                  2.37835700   -1.73989100    0.72925400
 H                  2.45123600   -0.53126900   -0.57585800
 O                  1.42731900   -2.30256300   -0.98373900
 C                  0.74519000   -1.78418300   -2.12126400
 H                  0.48529200   -2.62884100   -2.75986300
 H                 -0.17278400   -1.26104700   -1.82405200
 H                  1.38342200   -1.09036500   -2.68086100
 C                  4.78625500   -2.25258100   -1.79757500
 C                  5.26648800   -1.54183100   -0.70417300
 C                  5.24285700   -0.14651000   -0.73065700
 C                  4.74962600    0.53238600   -1.84103600
 C                  4.26935000   -0.19562200   -2.92962500
 C                  4.27465200   -1.59377400   -2.92427700
 H                  4.79520900   -3.33795600   -1.77203100
 H                  5.64788200   -2.06834100    0.16292700
 H                  4.72999500    1.61550100   -1.85802400
 H                  3.87741400    0.33553700   -3.79120500
 C                  3.73514900   -2.38566700   -4.08519900
 H                  3.27623000   -1.73934700   -4.83574300
 H                  4.53082400   -2.95743100   -4.57355500
 H                  2.98315600   -3.10527900   -3.74942100
 S                  5.73214400    0.76883400    0.74080500
 O                  4.52631700    0.79198700    1.63066300
 O                  6.12523100    2.13567700    0.28381800
 O                  6.86707900    0.01150100    1.35122100

